While saving a child from harm, otaku Asahi Ikusaba is transported to another world and believes he has reincarnated with cheat skills similar to those of the characters from his favorite games and novels. Unfortunately, reality strikes when an encounter with a powerful monster shows that he is still nothing more than an average person. In this moment of extreme danger, Asahi instinctively calls out to his overly doting sister, Maya, who appears out of nowhere, possessing the overpowered abilities he thought he had. Maya is ecstatic to see her brother again and resolves to use her newfound powers to protect Asahi no matter what. Together, the close-knit siblings attempt to find a way back home while enjoying their new lives. However, it soon becomes clear that their arrival in this world may have had a purpose. With the Demon King's overwhelmingly powerful army approaching, no one but Maya seems to be able to stand in its way.

Hime Shiraki appears to have it all: an angelic voice, an innocent personality, and an adorable face that enamors all onlookers. However, her cuteness is all a lie—it is purely an act to achieve her self-centered goal of marrying a rich suitor. Though she often plays up her innocence to gain favor from those around her, Hime's facade does not absolve her of responsibility when an accident leaves Mai Koshiba injured. Learning that Mai is the manager of Café Liebe—a cafe themed as an all-girls academy—Hime is coerced into taking up a part-time position until Mai recovers. However, Hime's facade cannot cover up her shortcomings at being a waitress, earning her the ire of one of her coworkers, Mitsuki Yano, the elegant "onee-sama" who often berates Hime over her mistakes. As Hime struggles to adjust to her new job in addition to Mitsuki's unrelenting hostility, her real personality begins seeping through the cracks.

After the events of Kimluck, Orphen is on a quest to find Azalie, only to find himself in a war in between celestial beings and humans.

Akane Nishimura's quiet nature makes her classmates perceive her as a gloomy and unlikeable person. Combined with her intimidating gaze, it earns Akane the ominous nickname "Grim Reaper," condemning her to endless bullying for her supposed cursed powers that bring misfortune to everyone around her. However, none of these rumors deter transfer student Taiyou Takada from trying to befriend Akane. As someone who finds the supernatural fascinating, Taiyou approaches the Grim Reaper without hesitation, blissfully unaware of the complicated situation within the class. His bright personality and optimistic worldview may just bring about the change that Akane desperately needs.